Metathesis as a versatile tool in oleochemistry

Olefin metathesis, awarded with the Nobel Prize in Chemistry 2005 for Chauvin, Grubbs and Schrock, has emerged as a powerful tool for organic as well as polymer chemistry. In oleochemistry, this reaction is well known and has been applied for many decades. Examples include the functionalization of the double bonds of different oleochemicals or the (direct) polymerization of plant oils via metathesis. More recent developments, particularly the development of better and more robust catalysts, allow for highly efficient cross‐metathesis reactions opening new possibilities for the direct introduction of chemical functionalities. Within this contribution, the development of metathesis in oleochemistry will be discussed, covering self‐metathesis as well as more recent developments in the field of cross‐metathesis that lead to desired platform chemicals.     

库车坳陷北带断裂输导天然气效率评价

在断裂输导天然气能力影响因素分析基础上,建立了断裂输导天然气能力评价参数.利用此评价参数对中国24个以断裂为主要输导通道的大中型气田断裂输导天然气能力进行了研究,并通过其天然气聚集效率和断裂输导天然气能力评价参数之间的关系研究得到:高效、中效和低效断裂输导天然气能力评价参数值应分别为大于250×10-4、250×10-4～25×10-4和小于25×10-4.根据库车坳陷北带断裂输导特征,对其下白垩统顶部断裂输导天然气效率进行了研究,得到库车坳陷北带下白垩统顶部高效断裂输导天然气区主要分布在大北1井周围、克拉1、2、3、4井周围和东秋5井-迪那2-依南2井周围3个地区,中、低效断裂输导天然气区围绕高效断裂输导天然气区分布.目前在该区发现的5个气田皆分布在高效断裂输导天然气分布区,表明高效断裂输导应是库车坳陷北带天然气成藏的重要条件.     

Effect of surfactants and liquid hydrocarbons on gas hydrate formation rate and storage capacity

Hydrate formation rate plays an important role in making hydrates for the storage and transport of natural gas. Micellar surfactant solutions were found to increase gas hydrate formation rate and storage capacity. With the presence of surfactant, hydrate could form quickly in a quiescent system and the energy costs of hydrate formation reduced. Surfactants (an anionic surfactant, a non‐ionic surfactant and their mixtures) and liquid hydrocarbons (cyclopentane and methylcyclohexane) were used to improve hydrate formation. The experiments of hydrate formation were carried out in the pressure range 3.69–6.82 MPa and the temperature range 274.05–277.55 K. The experimental pressures were kept constant during hydrate formation in each experimental run. The effect of anionic surfactant (sodium dodecyl sulphate (SDS)) on natural gas storage in hydrates is more pronounced compared to a non‐ionic surfactant (dodecyl polysaccharide glycoside (DPG)). The induction time of hydrate formation was reduced with the presence of cyclopentane (CP). Cyclopentane and methylcyclohexane (MCH) could increase hydrate formation rate, but reduced hydrate storage capacity The higher methylcyclohexane concentration, the lower the hydrate storage capacity. Copyright © 2003 John Wiley & Sons, Ltd.     

Preparation and Properties of Rare Earth Modified Carbon Black/Natural Rubber Composites

The oxides Eu, Ho, Er and Dy were used to prepare the hydroxides of rare earth modified carbon black. Then natural rubber latex （NRL） was added into the reactor. The system reacted at 85 ℃ with stirring for 1 h to prepare powdered HAF-Ln（OH）3/NR composites. The effects of the kind and content of Ln on the particle size distribution of P [ NR/HAF-Ln （OH）3 ] and mechanical properties of its vulcanizate were studied respectively. It is found that rare earth can help to get the powder of the composite, the product particle with a diameter less than 0.9mm will be get when the composites containing the compound of Ho, Er and Dy with dosage of 1.0, 1.0, O. 5 percent, respectively. The adding of Ln can improve the tensile strength and tear strength of the vulcanizate effectively, what＇s more, Er and Dy can decrease the permanent set of vulcanizate significantly. The SEM studies shows that P[ NR/HAF-Dy （OH）3 ] vulcanizate shows superior mechanical properties that depend primarily on the absence of free carbon black, the fine dispersion of carbon black in the rubber matrix and better polymer-filler interaction.     

Performance of natural‐fiber–plastic composites under stress for outdoor applications: Effect of moisture,temperature, and ultraviolet light exposure

The effects of moisture, temperature, and ultraviolet (UV) light on performance of natural‐fiber–plastic composites (NFPC) were assessed. We conducted short‐term tests in the laboratory and long‐term tests under natural exposure and measured changes in mechanical properties and color in samples of the composite. Chemical changes of the composite's materials were measured by X‐ray photoelectron spectroscopy to elucidate the mechanisms of chemical transformations on the material surface. Relative humidity highly affected the modulus of rupture (MOR) and the modulus of elasticity (MOE), and had a greater effect than temperature and UV exposure on performance of the composite. The lightness of the composite was increased by the UV effect in the short‐ and the long‐term tests. The X‐ray photoelectron spectroscopy (XPS) analysis suggested that the composite was protected by the UV absorber. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 2570–2577, 2006     

河北省水安全现状分析及对策探讨

从水资源与水环境两方面分析了河北省水安全的现状,指出影响水安全的因素在于自然因素、人为因素及人与自然的不协调因素,并针对水安全问题可能引发的健康安全、粮食安全、经济安全、生态环境安全进行了讨论,最后探讨了解决河北省水安全问题的对策。     

天然气管网输配气量优化研究

天然气管网系统管理部门为了明确天然气管网的输气能力和提高天然气管网的利用率，需要对天然气管网系统的输配气量进行优化。为此，以天然气管网系统的最大流量为目标函数，同时考虑了管道强度、节点压力和流量限制等约束条件，建立了天然气管网输配气量优化的数学模型。在研究遗传算法和模拟退火算法的基础上，提出了一种由二者结合构成的具有全域搜索、快速收敛和鲁棒性强等特点的混合遗传算法。结合实例，采用这一新算法求解了天然气管网输配气量优化的数学模型。实例优化结果表明，所建立的数学模型和采用的混合遗传算法是可行和有效的，能够对天然气管网系统输配气量的调度运行起到指导作用。     

关于从旋涡炉渣回收铜的研究

介绍了用自然澄清法降低、回收旋涡炉渣中的铜的方法。该方法工艺简单。操作方便，不仅降低冶炼成本，同时提高了经济效益。     

Contributions of Metaknowledge to Retrieval of Natural Categories in Semantic Memory.

Retrieving the answer to a general knowledge question has been shown to involve two metacognitive processes--a feeling-of-knowing that initiates the search of long-term memory and a willingness to continue searching until an answer can be confidently stated. To extend this model, college students were asked to retrieve as many members of 2 natural categories as they could in 1 min. Examination of the points at which they switched categories revealed that they searched longer in categories of higher potency, and they switched earlier when the other category was of higher potency. They also searched the first category longer when they were allowed to switch only once during a trial rather than as often as they wished. It was concluded that feeling-of-knowing maintained search of a category and also contributed to the willingness to continue searching, and the constraint on switching impacted the willingness to continue. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

谢尔渣油气化油改气控制系统的改造

介绍了Shell渣油气化装置将渣油原料改为天然气时控制系统的改造方案。提出的改造思路不但可用于Shell渣油气化，也可用于德士古渣油气化的油改气工程中。